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. 2016 Oct 26;120(51):29098–29106. doi: 10.1021/acs.jpcc.6b07555

Table 1. Kinetic and Relaxation Parameters Extracted from Fitting of the Build-up and Decay Curves for HEP, EA, ETMA, and EPy (Catalyst Concentration was 5 mM).

methanol HEP EA ETMA EPy
kr (s–1) 11.8 ± 1.8 11.5 ± 2.3 14.1 ± 2.5 2.8 ± 0.5
TS (s) 5.5 ± 0.2 7.2 ± 0.5 17.1 ± 1.2  
water HEP EA ETMA EPy
kr (s–1) 12.8 ± 3.9 14.4 ± 5.9 21.9 ± 4.2  
TS (s) 8.3 ± 0.8 4.3 ± 0.5 13.2 ± 1.4