TABLE 3.
Time (h) | Enantiomeric excess (%)a
|
Conversion (%)b | Enantiomeric ratioc | |
---|---|---|---|---|
Remaining ester | Product | |||
12 | 0 | NDd | 0 | |
24 | 23.2 ± 1.6 | 99.0 | 19.0 ± 1.0 | 250 |
36 | 39.1 ± 2.5 | 99.0 | 28.3 ± 1.3 | 292 |
Enantiomeric excess (ee) = 100 × (A − B)/(A + B), where A and B are enantiomers and A is greater than B.
Percentage of conversion (c) = ees/(ees + eep), where subscripts s and p represent remaining ester and product, respectively.
Enantiomeric ratio (E) = ln[1 − c(1 + eep)]/ln[1 − c(1 − eep)].
ND, not detected.