Table 1. Rate constants of hole transfer for (GT)n and (GA)n sequences.
(GT)n | kht*, 105 s-1 | (GA)n | kht*, 105 s-1 |
---|---|---|---|
2 | 11 | 2 | 570 |
3 | 5.9 | 3 | 230 |
4 | 2.2 | 4 | 130 |
6 | 0.67 | 6 | 31 |
8 | 0.31 | 8 | 13 |
12 | 0.12 | 12 | 6.2 |
Hole-transfer rate constants were determined by fitting the formation of PTZ·+ to a single-exponential function. Experimental error was estimated to be within 10%.