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. 2017 Jan 6;3(1):e1600615. doi: 10.1126/sciadv.1600615

Table 1. The TON of heterogeneous catalyst HB-Pd/C and homogeneous catalyst Pd(TFA)2 under different reaction conditions.

Under a low turnover condition, the substrate/catalyst ratio is 100:3; under a high turnover condition, the substrate/catalyst ratio is 1000:3; and under an ultrahigh turnover condition, the substrate/catalyst ratio is 10,000:3.

Entry Catalyst Low turnover High turnover Ultrahigh turnover
1 HB-Pd/C 31 314 >3000 (linear)
2 Pd(TFA)2 20 28