| Aglycone |
| 2a |
3.59 |
14.3 (2b) |
2b |
| 2b |
3.68 |
14.3 (2a) |
2a |
| 4a |
2.54 |
15.2 (4b), 5.3 (5) |
5, 4b |
| 4b |
2.63 |
15.2 (4a), 10.7 (5) |
4a |
| 5 (2H) |
1.92 |
5.3 (4a), 10.7 (4b), 7.6 (6) |
4a, 6 |
| 6 (2H) |
2.42 |
7.6 (5) |
5 |
| 8a |
2.43 |
14.5 (8b), 4.2 (9) |
8b, 9, 10a |
| 8b |
2.72 |
14.5 (8a), 9.0 (9) |
8a, 10b, 11 |
| 9 |
4.65 |
4.2 (8a), 9.0 (8b), 3.6 (10a), 8.4 (10b) |
8a, 10a, 11, 26 |
| 10a |
1.53 |
3.6 (9), 13.7 (10b), 3.6 (11) |
8a, 9, 10b, 11 |
| 10b |
1.77 |
8.4 (9), 13.7 (10a), 9.1 (11) |
8b, 10a, 11 |
| 11 |
4.27 |
3.6 (10a), 9.1 (10b), 4.0 (12a), 9.1 (12b) |
8b, 9, 10a, 10b, 13, 24, 26 |
| 12a |
1.52 |
4.0 (11), 14.7 (12b), 3.5 (13) |
12b, 13 |
| 12b |
1.79 |
9.1 (11), 14.7 (12a), 10.3 (13) |
12a, 14b |
| 13 |
4.75 |
3.5 (12a), 10.1 (12b), 3.5 (14a), 10.3 (14b) |
11, 12a, 14a, 22, 24 |
| 14a |
1.80 |
14.8 (14b), 3.5 (13) |
13, 14b, 16a |
| 14b |
2.00 |
14.8 (14a), 10.1 (13) |
12b, 14a, 16b |
| 16a |
1.78 |
13.5 (16b), 8.3 (17) |
14a, 18, 16b |
| 16b |
2.55 |
13.5 (16a), 4.6 (17) |
14b, 17, 16a |
| 17 |
5.02 |
8.3 (16a), 4.6 (16b), 10.5 (18) |
16b |
| 18 |
2.85 |
10.5 (17), 10.5 (19) |
16a, 19, 20a, 21 |
| 19 |
5.00 |
10.5 (18), 6.4 (20a), 2.3 (20b) |
18, 2’ |
| 20a |
2.11 |
6.4 (19), 14.9 (20b), 1.3 (21) |
18, 20b, 21 |
| 20b |
2.38 |
2.3 (19), 14.9 (20a), 5.1 (21) |
20a, 21, 1′ |
| 21 |
4.93 |
1.3 (20a), 5.1 (20b), 7.5 (22) |
18, 20a, 20b, 22, 23, 1’ |
| 22 |
6.37 |
7.5 (21), 15.0 (23) |
13, 21, 24 |
| 23 |
6.47 |
15.0 (22),11.0 (24) |
21, 25 |
| 24 |
6.64 |
11.0 (23), 16.0 (25) |
11, 13, 22, 26 |
| 25 |
6.94 |
16.0 (24), 11.0 (26) |
23, 28 |
| 26 |
6.46 |
11.0 (25), 11.0 (27) |
9, 11, 24, 27 |
| 27 |
6.93 |
11.0 (26), 11.0 (28) |
26, 30 |
| 28 |
6.75 |
11.0 (27), 11.0 (29) |
25, 29 |
| 29 |
6.32 |
11.0 (28), 11.0 (30) |
28, 31 |
| 30 |
7.18 |
11.0 (29), 16.0 (31) |
27, 32 |
| 31 |
6.47 |
16.0 (30), 11.0 (32) |
29 |
| 32 |
6.55 |
11.0 (31), 15.0 (33) |
30, 34 |
| 33 |
6.40 |
15.0 (32), 10.0 (34) |
35 |
| 34 |
6.23 |
10.0 (33), 15.0 (35) |
32, 36 |
| 35 |
5.64 |
15.3 (34), 9.0 (36) |
33, 36, 37, Me36 |
| 36 |
2.57 |
9.0 (35), 6.5 (Me36), 9.7 (37) |
34, 35, Me36 |
| 37 |
5.06 |
9.7 (36), 3.3 (38) |
35, 38, 39a, Me36 |
| 38 |
2.02 |
3.3 (37), 6.9 (Me38), 4.2 (39a), 7.6 (39b) |
37, Me38 |
| 39a |
1.37 |
4.2 (38), 16.3 (39b), 11.1 (40) |
37, 39b, Me38 |
| 39b |
1.79 |
7.6 (38),16.3 (39a), 4.0 (40), |
39a, 40, 41, 42a, Me40 |
| 40 |
2.00 |
11.1 (39a), 4.0 (39b), 7.3 (Me40), 8.7 (41) |
39b, 41, 42b, Me40 |
| 41 |
4.52 |
8.7 (40), 4.5 (42a), 8.4 (42b) |
39b, 40, 42a, 42b, Me38, B |
| 42a |
3.15 |
4.5 (41), 15.6 (42b) |
39b, 41, 42b, B |
| 42b |
3.40 |
8.4 (41), 15.6 (42a) |
40, 41, 42b, B |
| Me36 |
0.99 |
6.5 (36) |
35, 36, 37 |
| Me38 |
1.12 |
6.9 (38) |
38, 39a, 41 |
| Me40 |
1.01 |
7.3 (40) |
39b, 40 |
| COOMe |
3.79 |
— |
6′ |
| Aromatic protons |
| A (2H) |
6.97 |
8.7 (B) |
B |
| B (2H) |
8.16 |
8.7 (A) |
41, 42a, 42b, A |
| 3′-N-acetylmycosamine moiety |
| 1′ |
4.99 |
1.0 (2′) |
2′, 3′, 5′, 20b, 21 |
| 2′ |
4.45 |
1.0 (1′), 4.2 (3′) |
1′, 3′, 19 |
| 3′ |
4.69 |
4.2 (2′), 10.0 (4′) |
1′, 2′, 5′ |
| 4′ |
4.05 |
10.0 (3′), 9.4 (5′) |
5′, 6′, NH |
| 5′ |
3.77 |
9.4 (4′), 6.7 (6′) |
1′, 3′, 4′, 6′ |
| 6′ |
1.59 |
6.7 (5′) |
4′, 5′, COOMe |
| NH |
8.92 |
— |
4′, COMe |
| COMe |
2.11 |
— |
NH |
