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. Author manuscript; available in PMC: 2017 Sep 19.
Published in final edited form as: Inorg Chem. 2016 Sep 7;55(18):9297–9305. doi: 10.1021/acs.inorgchem.6b01390

Table 2.

Comparison of the Chemical Shifts (δ (ppm)) of the Ln3+-Bound Water and Amide Proton Resonances for the Series of LnDOTA–(gly)4 12,17 and LnDOTMA–(gly)4 Complexes (Obtained from CEST Spectra)

Ln3+ DOTA-(gly)4
DOTMA-(gly)4
H2O –NH H2O –NH
Pr −60 13 −85 15
Nd −32 11 −50 10
Sm −4 −13 6
Eu 50 −4 66 −4
Tb −600 62 −752
Dy −720 77
Ho −360 39
Er 200 −22
Tm 500 −51 −64
Yb 200 −16 −20