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. Author manuscript; available in PMC: 2017 Aug 26.
Published in final edited form as: Chemistry. 2016 Jul 26;22(36):12916–12930. doi: 10.1002/chem.201601468

Table 3.

X-ray structural parameters determining acetate binding mode in Zn2+ complexes.

Complex Nax-Zn-Nax Angle (°) Neq-Zn-Neq Angle (°) O-Zn-O Angle (°) OAc Binding Mode
[Zn2(AMD3100)(OAc)2]2+ 174.67 105.32 58.34 aniso-bidentate
[Zn28(OAc)2]2+ 158.40 117.91 56.31 aniso-bidentate
[Zn1(OAc)(H2O)]+ 171.89 83.44 88.70 monodentate/H2O
[Zn9(OAc)(H2O)]+ 169.88 83.52 89.52 monodentate/H2O
[Zn2(OAc)(H2O)]+ 157.59 81.80 90.83 monodentate/H2O