Table 5.
Entry | Catalyst | Loading | t-BuOOH | Yield/%a |
---|---|---|---|---|
1 | CuCl | 5 mol% | Yes | 90 |
2 | CuCl | 5 mol% | No | – |
3 | CuCl2 | 5 mol% | Yes | 78 |
4 | CuCl2 | 5 mol% | No | Traces |
5 | CuCl | 1 equiv. | No | – |
6 | CuCl2 | 1 equiv. | No | 35 |
aGC yield with dodecane as internal standard