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. Author manuscript; available in PMC: 2017 Oct 17.
Published in final edited form as: Inorg Chem. 2016 Sep 30;55(20):10800–10809. doi: 10.1021/acs.inorgchem.6b02109

Figure 2.

Figure 2

(a) Time-resolved UV−vis spectra (0–30 min) for the reaction of MnIV(O-B(C6F5)3)(TBP8Cz•+) (14 µM) with excess xanthene in CH2Cl2 at 23 °C. (b) Second-order plots for xanthene (blue squares) and xanthene-d2 (red squares) with MnIV(O-B(C6F5)3)(TBP8Cz•+). KIE = kH/kD = 25 ± 2. (c) Dependence of the log k values for MnIV(O-B(C6F5)3)(TBP8Cz•+) on the BDE values of the scissile C−H bond. Slope = −0.76 ± 0.05.