Table 1.
Reaction | Gibbs free energy (ΔG 0, kJ mol−1) |
---|---|
(1) CH4 + SO4 2− → HCO3 − + HS−+ H2O | −16.3 |
(2) CH4 + 4 NO3 − → HCO3 − + 4 NO2 − + H2O + H+ | −517.2 |
(3) CH4 + 8 Fe(OH)3 + 16 H+ → CO2 + 8 Fe2+ + 22 H2O | −571.2 |
(4) CH4 + 4 MnO2 + 8 H+ → CO2 + 4 Mn2+ + 6 H2O | −763.2 |
(5) CH4 + 4/3 Cr2O7 2− + 32/3 H+ → 8/3 Cr3+ + CO2 + 22/3 H2O | −841.4 |