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. Author manuscript; available in PMC: 2018 Jan 11.
Published in final edited form as: J Am Chem Soc. 2016 Dec 28;139(1):472–481. doi: 10.1021/jacs.6b11322

Figure 7.

Figure 7

Scheme (top) and UV–vis spectra showing (A) formation and 1e reduction reactivity of FeIV=O in the presence of 4-NO2–phenol. Initial rates (B) and UV–vis spectra (C) for formation of 1 equiv of Fc*+ in the reduction of Cmpd II (blue) and 2 equiv of Fc*+ for [LS-4DCHIm(ArOH)] (green).