Table 2.
m/e | Ion | 50 volts | 20 volts | 15 volts |
---|---|---|---|---|
|
|
|
|
|
41 | B(CH3)2 | 21.7 | 0.05 | 0.05 |
61 | P(CH3)2 | 4.6 | .45 | .25 |
75 | BH3P(CH3)2 | 17.5 | ………….. | ………….. |
89 | BHP2(CH3) | 14 | ………….. | ………….. |
(a) | (a) | (a) | (a) | (a) |
261 | B4H3P4(CH3)6 | 4.9 | 4.4 | ………….. |
262 | B4H4P4(CH3)6 | 5.1 | 5.4 | 1.95 |
263 | B4H5P4(CH3)6 | 12.4 | 14.4 | 4.15 |
264 | B4H6P4(CH3)6 | 1.45 | 1.21 | 0 |
265 | B4H7P4(CH3)6 | 3.0 | 3.2 | 1.05 |
273 | B4P4(CH3)7 | 5.15 | 8.0 | 1.10 |
274 | B4HP4(CH3)7 | 1.90 | 1.53 | 0.55 |
275 | B4H2P4(CH3)7 | 9.25 | 9.10 | 3.0 |
276 | B4H3P4(CH3)7 | 4.75 | 4.82 | 1.65 |
277 | B4H4P4(CH3)7 | 14.3 | 14.9 | 5.75 |
278 | B4H5P4(CH3)7 | 5.90 | 5.85 | 3.6 |
279 | B4H6P4(CH3)7 | 7.60 | 7.90 | 4.25 |
287 | B5H3P4(CH3)7 | 6.25 | 5.90 | 2.0 |
288 | B5H4P4(CH3)7 | 0.95 | 0.85 | 0 |
289 | B5H5P4(CH3)7 | 19.9 | 20.0 | 11.9 |
290 | B5H6P4(CH3)7 | 3.9 | 4.0 | 2.15 |
291 | B5H7P4(CH3)7 | 9.2 | 11.0 | 7.5 |
292 | B5H8P4(CH3)7 | 4.1 | 3.56 | 3.9 |
293 | B5H9P4(CH3)7 | 5.5 | 7.1 | 5.25 |
322 | B4H3P5(CH3)8 | 1.76 | 1.35 | ………….. |
323 | B4H4P5(CH3)8 | 2.54 | 2.07 | 2.3 |
324 | B4H5P5(CH3)8 | 36.6 | 35.1 | 39.0 |
325 | B4H6P5(CH3)8 | 19.0 | 16.2 | 18.0 |
326 | B4H7P5(CH3)8 | 7.7 | 8.5 | 9.4 |
327 | B4H8P5(CH3)8 | 2.62 | 1.67 | 1.85 |
334 | B4P5(CH3)9 | 1.08 | 1.13 | 0.90 |
335 | B4HP5(CH3)9 | 4.90 | 4.50 | 2.45 |
336 | B4H2P5(CH3)9 | 3.30 | 2.43 | 2.20 |
337 | B4H3P5(CH3)9 | 3.84 | 3.96 | 4.40 |
338 | B4H4P5(CH3)9 | 19.4 | 19.4 | 19.5 |
340 | B4H6P5(CH3)9 | 100 | 100 | 100 |
347 | B5H2P5(CH3)9 | 2.72 | 2.34 | 1.70 |
348 | B5H3P5(CH3)9 | 2.48 | 0.95 | 2.15 |
349 | B5H4P5(CH3)9 | 4.15 | 2.48 | 1.50 |
350 | B5H5P5(CH3)9 | 17.9 | 16.6 | 20.5 |
351 | B5H6P5(CH3)9 | 4.1 | 1.80 | 3.35 |
352 | B5H7P5(CH3)9 | 87. | 84.1 | 105 |
353 | B5H8P5(CH3)9 | 3.84 | 2.48 | 3.05 |
354 | B5H9P5(CH3)9 | 26.4 | 18.0 | 13.9 |
Mass range 90 to 260 omitted. Ions have not been identified.