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. 1961 Aug 1;65A(4):297–336. doi: 10.6028/jres.065A.035

Figure 6. The coherent chain folded surface nucleus model of spherulitic growth and its rate behavior.

Figure 6

(a)Lamella with folded coherent nucleus of length l, width a, and monomolecular layer thickness b0 on its surface. Heavy arrow marked G, indicates direction of radial growth of lamellar spherulite. Arrow s−s′ indicates axis of spiral dislocation. Chain y−y′ indicates molecule incorporated bundle fashion into lamella.

(b)Schematic diagram illustrating cause of a certain value of the step height, l*, giving maximum surface nucleation rate.

(c) Logarithm of radial growth rate of spherulite as function of temperature.––––log G versus T if jump rate effect is small;——most representative case where jump rate lowers log G causing maximum to appear near (Tm+Tg)/2;…. exhibits effect of excess nucleation rate in medium surrounding spherulite.