Table 10.
Polymer | Number of peaks | Spacings | Width overall | Yield, G(R) |
---|---|---|---|---|
|
|
|
|
|
Gaussa | Gauss | Radicals/100 ev | ||
PTFEb | c10 or 11 | −96, −67, −40, −18, −13, (−3, +4) +13, +23, +42, +71, +97 | 220 | 0.15, 0.19 |
TFE-HFPb | 11 | −88, −67, −40, −20. −11, (−5, +2), +12, +22, +40, +67, +93 | 220 | 1.1 |
PCTFEd | 3 | −100, (−5, +5), +100 | 350 | 0.99 |
PTrFEd | e5 | −171e, −94, (−29, +29)e, +94, +156e | 425 | .74 |
PTFSd | 3 | −52, (−18, +19) +51 | 220 | .57 |
PPFSd | 1 | ………. | 140 | .11 |
Derivative peak locations; pair in parentheses due to single center component.
Irradiated at 20 °C.
Varies with orientation, identity and age.
Irradiated at −80 °C; observed at 25 °C.
Very weak shoulders.