Table 3.
M/MF2‐NP size and size distribution.[a]
| Precursor | M/MFx‐NPs | TEM Ø (σ) [nm][b] | PXRD Ø (σ) [nm][b,c] |
|---|---|---|---|
| [BMIm][BF4][a] | |||
| Mn(AMD)2 | MnF2 | 15(±4) | 14(±3) |
| Fe(AMD)2 | FeF2 | 65(±18) | 73(±3) |
| Co(AMD)2 | CoF2 | 43(±11) | 47(±5) |
| Ni(AMD)2 | Ni | 11(±3) | 12(±3) |
| Cu(AMD) | Cu | 14(±4) | 17(±3) |
| [BMIm][Tos][a] | |||
|---|---|---|---|
| Mn(AMD)2 | –[d] | – | – |
| Fe(AMD)2 | Fe | 11(±2) | – |
| Co(AMD)2 | Co | 7(±4) | – |
| Ni(AMD)2 | Ni | 12(±4) | 13(±2) |
| Cu(AMD) | –[d] | – | – |
| PC[a] | |||
|---|---|---|---|
| Mn(AMD)2 | Mn | 4(±2) | –[e] |
| Fe(AMD)2 | Fe | 2(±2) | –[e] |
| Co(AMD)2 | Co | 4(±2) | – |
| Ni(AMD)2 | Ni | 8(±5) | 12(±2) |
| Cu(AMD) | Cu | 51(±8) | 55(±7) |
[a] 1.0 wt % M‐NP/[BMIm][BF4], M‐NP/[BMIm][Tos], or M‐NP/PC dispersion obtained by microwave irradiation with 50 W for 10 min (40 min for PC) at 240 °C. [b] Average diameter (Ø) and standard deviation (σ). See the Experimental Section for TEM measurement conditions. [c] From the Scherrer equation, Scherrer‐factor: 0.95.53 [d] No particles were obtainable. [e] No precipitation possible.