Table 1. Scope of Potassium Alkoxymethyltrifluoroborates in Cross-Coupling with Hydrocinnamoyl Chloride.
Reaction completed on 5.9 mmol scale with 1 mol % Ir photocatalyst and 2 mol % NiCl2·dme/L1.
Determined by SFC using L1 under the optimized conditions.
Determined by SFC using 4 mol % L2 as a ligand at −25 °C. er = enantiomeric ratio.