Table 1. Comparison of selected bond lengths, bond angles and torsion angles (Å, °).

	(bipy)(mebzimpy)chlorido­iridium(III)(PF6)2 (Yutaka et al., 2005 ▸) (geometry: slightly distorted octa­hedral)	Title complex (geometry: slightly distorted octa­hedral)
Bond Length
Ir—Cl	2.338 (3)	2.3510 (9)
Ir—N1	2.039 (8)	2.032 (3)
Ir—N3	1.991 (8)	1.992 (3)
Ir—N5	2.032 (9)	2.037 (3)
Ir—N6	2.046 (9)	2.050 (3)
Ir—N7	2.049 (9)	2.057 (3)
Bond Angles
N3—Ir—N5	78.9 (3)	80.34 (13)
N3—Ir—N7	178.5 (4)	178.09 (13)
N6—Ir—N7	81.0 (4)	79.55 (12)
N1—Ir—N5	156.3 (3)	158.99 (13)
N3—Ir—N6	103.4 (2)	99.62 (12)
Torsion Angles
N1—C7—C8—N3	0 (1)	−6.6 (5)
N3—C12—C13—N5	−1 (1)	−1.1 (5)
N6—C32—C33—N7	4 (1)	7.3 (5)

Atom labels correspond to atoms of the title complex, analogous relationships reported by Yutaka et al. (2005 ▸) were compared.