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. 2017 Jan 17;114(5):864–869. doi: 10.1073/pnas.1620870114

Scheme 1.

Scheme 1.

Sulfur photochemistry in an anoxic early atmosphere. Sulfur is emitted to the atmosphere from volcanoes as sulfur dioxide and hydrogen sulfide, and is removed by rainout of soluble gases and by formation and deposition of sulfate and elemental sulfur particles.