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. 2017 Feb 9;7:42174. doi: 10.1038/srep42174

Table 3. Values of the fitting parameters of the activation volumetric EOS by fitting the activation volumes evaluated using the MYEGA model to Eq. (9) with Eqs (10) and (11).

LC system (phase) F0(cm3/mol) F1(cm3/mol/K) F2/10#x02212;4(cm3/mol/K2) Bact(T0, p0) (MPa) g2/10−3(K−1) γact γact from Eq. (19)
6BT (Cr E) 42.97 ± 0.11 0.1871 ± 0.0003 0.00 ± 0.15 998.9 ± 5.6 0.214 ± 0.067 0.981 ± 0.023 0.982
8BT (Cr E) 61.38 ± 0.01 0.2090 ± 0.0002 −6.11 ± 0.05 432.92 ± 0.21 0.409 ± 0.014 1.109 ± 0.004 1.105
7CB (N) 61.27 ± 0.50 2.138 ± 0.056 26.1 ± 1.8 73.69 ± 0.36 4.42 ± 0.38 0.518 ± 0.007 0.512
7PCH (N) 66.59 ± 0.06 1.315 ± 0.007 35.7 ± 2.2 121.22 ± 0.25 1.89 ± 0.13 0.59 ± 0.01 0.59
8PCH (N) 66.41 ± 0.18 2.386 ± 0.017 24.1 ± 3.1 67.72 ± 0.20 0 0.363 ± 0.003 0.367
8OCB (N) 74.98 ± 0.07 1.392 ± 0.007 21.5 ± 1.2 113.75 ± 0.17 0 0.459 ± 0.002 0.459

The reference state is fixed at the phase transition temperature T0 (shown in Table 1) at ambient pressure p0 = 0.1 MPa. The fitted value of γact is compared with that calculated from Eq. (19) for each material.