. 2016 Dec 29;89(3):1583–1592. doi: 10.1021/acs.analchem.6b03620

Table 1. Reaction Stoichiometries with Ir^OX/Ir(IV).

reductants	reaction stoichiometry with Ir^OX/Ir(IV)	ref
glutathione (GSH)	6 Ir(IV) + GSH + 3H₂O → 6 Ir(III) + GSO₃^– + 7H⁺	(37)
glutathione (GSH)	2 Ir(IV) + 2GSH → 2 Ir(III) + GSSG + 2H⁺	(37)
ascorbate	2 Ir(IV) + H₂A → 2 Ir(III) + A + 2H⁺	(38)
cysteine	6 Ir(IV) + HSCH₂CHNH₃COO^– + 3H₂O → 6 Ir(III) + HO₃SCH₂CHNH₂COO^– + 7H⁺	(39,45)
quinols	2 Ir(IV) + H₂Q → 2 Ir(III) + Q + 2H⁺	(73)

Table 1. Reaction Stoichiometries with IrOX/Ir(IV).