Table 4.
4a | ||
Test material | Low pH | Neutral pH |
Bulk-Zn metal | Biopersistent | Biopersistent |
Nano-Zn metal | Soluble | Biopersistent |
Bulk-ZnO | ||
Nano-ZnO100 nm | Soluble | Biopersistent |
Nano-ZnO50 nm | ||
Bulk-anatase | ||
Nano-anatase | Biopersistent | Biopersistent |
Bulk-rutile | ||
Nano-rutile | ||
4b | ||
Solubility category | Low pH | Neutral pH |
High solubility (>70 %) | Bulk-ZnO (88.5 %) | |
Nano-ZnO100 nm (97 %) | ||
Nano-ZnO50 nm (94 %) | ||
Nano-Zn metal (80.8 %) | ||
Moderate solubility (10–70 %) | Bulk-Zn metal (17.5 %) | |
Low solubility (1–10 %) | Nano-Zn metal (1.33 %) | |
Bulk-Zn metal (2.05 %) | ||
Nano-ZnO50 nm (2.13 %) | ||
Nano-ZnO100 nm (1.87 %) | ||
Negligible solubility (<1 %) | Bulk-ZnO (0.95 %) | |
Bulk-anatase (0.019 %) | Bulk-anatase (<0.0001 %) | |
Nano-anatase (0.022 %) | Nano-anatase (<0.0001 %) | |
Bulk-rutile (0.0001 %) | Bulk-rutile (<0.0001 %) | |
Nano-rutile (0.0002 %) | Nano-rutile (<0.0001 %) |