. 2016 Aug 1;8(1):189–199. doi: 10.1039/c6sc02721k

Table 2. Selected bond lengths (Å) ^a , inner angles (deg) ^a , MPD (Å), and interporphyrin separation (Å) for 13, [13]⁺, 14, and [14]⁺ from crystal structures.

	N–C_meso	N–C_Ph	∠C_meso–N–C_Ph	∠C_Ph–N–C_Ph′	MPD	Interporphyrin separation
13 ^b	1.393(4)	1.413(2)	121.1(2)	117.9(3)	0.104	3.511
[13]⁺	1.396(7)	1.425(7)	120.8(5)	118.4(7)	0.092	3.354
14 ^b	1.401(5)	1.423(4)	119.7(2)	120.5(3)	0.398	3.390
[14]⁺	1.388(10)	1.423(6)	120.2(4)	119.7(6)	0.409	4.212–4.353

^aThe values were averaged for C _2v symmetry. The estimated standard deviations of mean values were calculated from the experimental values using the following equation: δ(l) = 1/(Σ(1/δ _i ²))^1/2.

^bThe values were averaged for two crystallographically independent molecules. The estimated standard deviations of mean values were calculated from the experimental values using the following equation: δ(l) = 1/(Σ(1/δ _i ²))^1/2.

Table 2. Selected bond lengths (Å) a , inner angles (deg) a , MPD (Å), and interporphyrin separation (Å) for 13, [13]+, 14, and [14]+ from crystal structures.

Table 2. Selected bond lengths (Å) ^a , inner angles (deg) ^a , MPD (Å), and interporphyrin separation (Å) for 13, [13]⁺, 14, and [14]⁺ from crystal structures.