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. 2015 Jan 20;5(1):90–114. doi: 10.3390/nano5010090

Table 1.

Processing details of CNTs-reinforced ceramics nanocomposites.

Reference Matrix CNT types Purification methods Dispersion procedures Sintering techniques
[10] Si3N4 SW P UT of CNTs with surfactant (C16TAB) and Si3N4 SPS under vacuum
[12] Al2O3 MW Oxidation at 500 °C for 90 min UT of CNTs in ethanol SPS at 1500 °C for 10 min under 50 MPa
[32] Al2O3 MW AT (H2SO4 + HNO3) UT of CNTs into water and SDS then incubation for 2 weeks HP at 1600 °C, 60 min, 40 MPa
[33] Al2O3 MW AT (H2SO4 + HNO3) for 3 h 24 h BM of ball Al2O3 powder and 30 min UT of CNTs in water and then BM of CNTs/Al2O3 mixture PLS at 1500–1600 °C, 120–240 min, Ar
[34] Al2O3 MW Pristine UT of CNTs for 1 h in alcohol CIP at150MPa and PLS at 1500 °C, and 1700 °C with 2 h
[35] Al2O3 MW AT (heating in 65% HNO3 at 80 °C for 8 h) BM and Surfactant (Darvan C–N) PLS at 1500 °C for 2 h using Ar
[36] Mulite MW P CNTs dispersion into ethanol by MS and UT HP at 1600 °C for 60 min under Ar atmosphere at 30 MPa
[37] Si3N4 MW P 24 h ball milling the CNTs and Si3N4 slurry HP at 1750 °C for 60 min under 30 MPa
[38] ZrB2–SiC MW P 20 min UT of CNTs and matrix with subsequent 24 h ball milling HP at 1900 °C for 60 min under 30 MPa
[39] BaTiO3 MW P - HP, 1200 °C, 60 min
[40] Al2O3 MW - DG (CVD at 750 °C for 15 min for direct CNTs growth on Al2O3 nano-particles) SPS at 1150 °C for 10 min under 100 MPa
[41] Al2O3 SW Pristine UT of CNTs in ethanol SPS at 1520 °C under 80 MPa
[42] Al2O3 MW P 35 h UT in water SPS at 1300 °C, 20 min, 90 MPa
[43] Al2O3 MW AT UT of CNTs and Al2O3 in water followed by 2 h and BM of CNTs/Al2O3 PLS at 1600 °C, 15 min, Ar
[44] Al2O3 MW AT (HNO3 for 30 min) 5 h BM of CNTs and 1 h UT of CNTs. 5 h BM of CNT/Al2O3 in ethanol PLS at 1550 °C, Ar
[45] Al2O3 MW AT (H2SO4 + HNO3 in 3:1 for 7 h) surfactant (SDS) using combination of UT and 24 h BM HP at 1550 °C for 1 h under 30 MPa using Ar gas
[46] Al2O3 + ZrO MW AT (heating in 65% HNO3 at 80 °C for 8 h)) 2 min UT of CNTs with surfactant (SDS)and 24 BM then freezing with Nitrogen HP at 1500 °C for 2 h under 30 MPa in Ar atmosphere
[47] Al2O3 SW AT (H2SO4 + HNO3) UT for 24 h SPS at 1300 °C for 5 min under 75 MPa

Notes: SW: Single-walled CNTs; MW: Multi-walled CNTs; UT: Ultrasonication; BM: Ball milling; HP: Hot-pressing; SPS: Spark plasma sintering; PLS: Pressureless sintering; SDS: Sodium dodecyle sulphate; CIP: cold isostatic pressing; P: Pristine; MS: Magnetic stirring.