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Water-corrected drop solution enthalpies versus molar surface area. Surface enthalpy of the hydrous surface is 0.77 ± 0.10 J/m2 for cryptomelane (A), 0.69 ± 0.13 J/m2 for sodium birnessite (B), 0.55 ± 0.11 J/m2 for potassium birnessite (C), and 0.41 ± 0.11 J/m2 for calcium birnessite (D).