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Van der Waals (solid line) and electrostatic (open symbols, dashed lines) contributions to the free energy. The long-range contribution to free energy is uniquely decomposable11,63 into electrostatic and van der Waals contributions because P(ε|ϕ) = P(εvdw|ϕ) × P(εelec|ϕ), where ε = εvdw + εelec, i.e., the individual binding energy distributions are uncorrelated.
