Table 4.
Functional group associated with precipitates made from the acidification of hydrolysis and soda liquors generated after 45 min of the hydrolysis treatment
Temperature °C | Precipitates of hydrolysis liquor (mmol/g) | Precipitates of soda liquor (mmol/g) | ||||
---|---|---|---|---|---|---|
170 | 180 | 190 | 170 | 180 | 190 | |
Aliphatic OH | 2.04 | 1.54 | 0.75 | 1.05 | 1.14 | 0.53 |
C5 substituted | 0.33 | 0.23 | 0.07 | 0.35 | 0.19 | 0.24 |
Guaiacyl OH | 1.42 | 1.61 | 0.94 | 1.22 | 1.14 | 0.86 |
p-Hydroxy phenyl | 0.08 | 0.06 | 0 | 0.1 | 0.03 | 0.02 |
Carboxylic | 0.14 | 0.14 | 0.06 | 0.71 | 0.67 | 0.53 |
Total | 4.01 | 3.58 | 1.81 | 3.43 | 3.17 | 2.18 |