Table 5.

Number of drop experiments, N_drop, the molar heat capacity, $C_{p,\mathrm{m}}^{\mathrm{o}}(\text{J}\cdot {\text{K}}^{-1}\cdot {\text{mol}}^{-1}),$ specific heat capacities, $c_p^{\mathrm{o}}(\text{J}\cdot {\text{K}}^{-1}\cdot {\text{g}}^{-1}),$ and volumic heat capacities, $C_p^0/V(\text{J}\cdot {\text{K}}^{-1}\cdot {\text{cm}}^{-3})$ at 298.15 K.

Ionic Liquid	Ndrop	$C_{p,\mathrm{m}}^{\mathrm{o}}(\text{J}\cdot {\text{K}}^{-1}\cdot {\text{mol}}^{-1}),$	$C_p^0(\text{J}\cdot {\text{K}}^{-1}\cdot {\text{g}}^{-1}),$	$C_p^{\mathrm{o}}/V(\text{J}\cdot {\text{K}}^{-1}\cdot {\text{cm}}^{-3})$
[1C1Him][NTf2] (cr)	12	441.64 ± 0.33	1.2158 ± 0.0009	1.9785 ± 0.0015
[1C2Him][NTf2] (l)	33	484.08 ± 0.44	1.2831 ± 0.0012	2.0055 ± 0.0019
[1C23C3im][NTf2] (l)	19	565.08 ± 0.57	1.3475 ± 0.0014	1.9342 ± 0.0020
[1C12C1Him][NTf2] (l)	23	483.08 ± 0.38	1.2804 ± 0.0010	2.0113 ± 0.0016