Table 6.
Experimental refractive indices at the sodium D-line, nD a, for the studied ILs as a function of temperature T at 0.1 MPa. Available literature data at T = 298.15 K.
Ionic liquid | nD (298.15 K) | 104·(dnD/dT) / K-1 | nD (298.15 K) Literature |
---|---|---|---|
[1C1Him][NTf2] | 1.42203 | -2.93 ± 0.01 | n.a. |
[1C2Him][NTf2] | 1.42317 | -3.012 ± 0.002 | n.a. |
[1C12C1Him][NTf2] | 1.42490 | -2.959± 0.003 | n.a. |
[1C13C1im][NTf2] | 1.42101 | -2.97 ± 0.02 | n.a. |
[1C23C1im][NTf2] | 1.42319 | -2.99 ± 0.01 | 1.4230(9)58 1.422047 1.4225148 1.4230749–51 1.4229852 |
[1C33C1im][NTf2] | 1.42534 | -3.02 ± 0.01 | 1.4252553 |
[1C23C2im][NTf2] | 1.42512 | -3.04 ±0.02 | n.a. |
[1C23C3im][NTf2] | 1.42668 | -3.08 ± 0.01 | n.a. |
[1C43C1im][NTf2] | 1.42705 | -3.10 ± 0.01 | 1.4265348 1.4269254,55 1.42756 1.451 57 1.4267250,51 |
[1C33C3im][NTf2] | 1.42805 | -3.10 ± 0.01 | n.a. |
in the temperature interval, nD, at a specific temperature, T, can be estimated using the following equation: nD(T / K) = nD (298.15 K) + dnD/dT·(T / K - 298.15 K).