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. 1964 Jun 1;68A(3):305–312. doi: 10.6028/jres.068A.028

Table 4.

Medium effects on pK for o-chlor oanilinium ion, m-nitroanilinium ion, and 4-chloro-2,6-dinitrophenol in methanol-water solvents at 25 °C

N2 p(sK)−p(wK) for



o-Chloroanilinium m-Nitroanilinium 4-Chloro-2,6-dinitrophenol




0    0 0 0
0.1 −0.15 −0.17 +0.12
0.2   −.35   −.45   +.19
0.3   −.58   −.69   +.25
0.4   −.75   −.90 …………………
0.5   −.86 −1.00 …………………
0.6   −.92 −1.05 …………………
0.7   −.93 −1.07 …………………
0.8   −.81 −1.03 …………………
0.9   −.42 −0.74 …………………
 0.999 +0.75 ………………… …………………