Table 1.

¹H NMR and ¹³C NMR spectral data (400MHz for δ_H, 125 MHz for δ_C, δ in ppm, J values in Hz) for compounds (1–3) in Pyridine-d₅.

	(1)		(2)		(3)
Position	δH	δC	δH	δC	δH	δC
1	1.02m, 1.53m	39.7	1.36, m	39.4	1.36, m	39.4
2	1.81m	27.1	1.80, m	27.1	1.80, m	27.1
3	4.33	81.7	3.22, m	90.7	3.19, m	90.7
4	–	44.2	–	40.3	–	40.3
5	1.73, m	48.1	0.74, m	56.3	0.74, m	56.3
6		18.8	1.39, m	18.8	1.39, m	18.8
7	1. 27 m, 1.61 m	33.1	2.13, m	35.7	2.13, m	35.7
8	–	40.5	–	41. 5	–	41. 5
9		48.7		47.5		47.5
10	–	37.5	–	37.4	–	37.4
11	1.89, m	23.9	1.74, m	24.4	1.74, m	24.4
12	5.42, bs	123.6	5.44, bs	124	5.44, bs	124
13	–	144.8		144.3		144.3
14	–	42.8	–	44.8	–	44.8
15	1.17, m	28.9		33.7		33.7
16	1.89, m	24.5		70.4		70.4
17	–	47.7	–	42.3	–	42.3
18	3.17, m	42.3		na		na
19	1.18, m	46.7	2.87, m	48.1	2.87, m	48.1
20	–	30.6	–	32.6	–	32.6
21	1.03, m	34.6	2.06,m, 2.85,m	42.2	2.85, m	42.2
22	1.28, m	33.3	6.22, m	72.7	6.22, m	72.7
23	3.94m, 4.33 m	64.7	1.19, s	17. 4	1.19, s	17. 4
24	1.15, s	14.8	1.24, s	28.6	1.24, s	28.6
25	0.99, s	16.9	0.84, s	16.3	0.84, s	16.3
26	1.13, s	18.3	0.91, s	16.4	0.91, s	16.4
27	1.21, s	26.8	1.88, s	28.2	1.88, s	28.2
28	–	17 7. 3	3.59, 3.74, m	64.3	3.59, 3.74, m	64.3
29	0.89, s	33.8	1.08, s	34.1	1.08, s	34.1
30	0.90, s	24.4	1.32, s	25.9	1.32, s	25.9
Angeloyl
1			–	168.7	–	168.7
2			–	130	–	130
3			5.95, d	137. 2	5.95, d	137. 2
4			2.13, d, 5.6	17. 5	2.13, d, 5.6	17. 5
5			2.01, s	21.7	2.01, s	21.7
3-O-Sugar
	Xylose-1		Glucose-1		Glucose-1
1‵	5.09, d, 6.5 Hz	105.3	4.79, d, 5.2	105.3	4.79, d, 5.2	105.3
2‵	4.03, m	75.6	4.15, m	76.4	4.15, m	76.4
3‵	4.13, m	76.2	4.23, m	76.3	4.23, m	76.3
4‵	4.12, m	71.3	4.33, m	72.6	4.33, m	78.2
5‵	3.68, 4.45, m	67.9	4.12,m	77	4.12,m	77
6‵			4.36, 4.68, m	61.9	4.36, 4.68, m	61.9
	Rhamnose-1		Rhamnose		Rhamnose
1‵‵	6.33, s	101. 9	6.14, s	103.6	6.18, s	103.8
2‵‵	4.88, bs	71.7	4.88, bs	72	4.88, bs	72
3‵‵	4.81, m	83.3	4.81, m	83.3	4.72, m	73.5
4‵‵	4.45, m	73.2	4.45, m	72.9	4.45, m	72.9
5‵‵	4.71, m	70.4	4.71, m	70.2	4.71, m	70.2
6‵‵	1.58, d, 5.6	19.2	1.58, d, 5.6	19.2	1.58, d, 5.6	19.2
	Xylose-2		Glucose-2
1‵‵‵	5.35, d, 7. 5 Hz	10 7. 9	5.21, d, 5.6 Hz	104.9
2‵‵‵	4.09, m	73.3	3.95, m	76.4
3‵‵‵	4.18, m	75.9	4.14, m	78.6
4‵‵‵	4.22, m	71	4.44, m	70.8
5‵‵‵	3.71, 4.49, m	66.9	3.66, m	77.9
6‵‵‵			4.08, 4.22, m	61.9
23-O-sugar
	Glucose-1
1‵‵‵‵	5.01, d, 7. 5 Hz	105.4
2‵‵‵‵	4.15, m	75.9
3‵‵‵‵	4.23, m	74.6
4‵‵‵‵	4.33, m	72.6
5‵‵‵‵	4.12, m	77.1
6‵‵‵‵	4.36, 4.68, m	61.9
28-O-sugar
	Glucose-2
1‵‵‵‵‵	6.24, d, 8Hz	96.3
2‵‵‵‵‵	3.95, m	75.9
3‵‵‵‵‵	4.14, m	78.9
4‵‵‵‵‵	4.44, m	70.3
5‵‵‵‵‵	3.66, m	77.7
6‵‵‵‵‵	4.08, 4.22, m	69.7
	Rhamnose-2
1‵‵‵‵‵‵	5.84, s	103.4
2‵‵‵‵‵‵	4.68, m	71.7
3‵‵‵‵‵‵	4.56, m	73.2
4‵‵‵‵‵‵	4.35, m	74.5
5‵‵‵‵‵‵	4.93, m	71
6‵‵‵‵‵‵	1.7, d, 5.6	19.1