Table 3.
|
Amide 1 |
Amine 2 |
Amine 3 |
Amine 4 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Solvent | ET30 | Amax nm | Emmax nm | Δν cm−1 | Amax nm | Emmax nm | Δν cm−1 | Amax nm | Emmax nm | Δν cm−1 | Amax nm | Emmax nm | Δν cm−1 |
Dioxane | 36 | 399 | 446 | 2640 | 426 | 489 | 3020 | 472 | 540 | 2670 | 486 | 546 | 2260 |
Ethyl Acetate | 38.1 | 399 | 446 | 2640 | 426 | 501 | 3510 | 472 | 552 | 3070 | 483 | 552 | 2590 |
Acetone | 42.2 | 398 | 460 | 3390 | 429 | 522 | 4150 | 481 | 575 | 3400 | 487 | 574 | 3110 |
DMSO | 45.0 | 401 | 481 | 4150 | 452 | 548 | 3880 | 498 | 591 | 3160 | 510 | 595 | 2800 |
Isopropanol | 48.6 | 395 | 468 | 3950 | 446 | 542 | 3970 | 497 | 579 | 2850 | 513 | 576 | 2130 |
Ethanol | 51.9 | 395 | 482 | 4570 | 441 | 540 | 4160 | 501 | 580 | 2720 | 515 | 584 | 2290 |
Methanol | 55.5 | 395 | 496 | 5160 | 442 | 542 | 4120 | 503 | 582 | 2740 | 518 | 588 | 2260 |
Water | 63.1 | 407 | 521 | 5380 | 430 | 560 | 5400 | – a | – | – | 545 | 612 | 2010 |
Amine 3 was insoluble in water