Table 1. The PL decay effective lifetime ( ) and quantum yield ( η PL) at injected carrier density of around 1015 cm−3, Trap states density ( η Trap ), First order (k 1), Second order (k 2), and Third order (three-particle Auger) recombination constant (k 3), Biexciton Auger recombination coefficient ( C bx ).
(ns) | η | ηTrap (cm−3) | k1 (s−1) | k2 (cm3 s−1) | k3 (cm6 s−1) | Cbx (cm2 s−1) | |
---|---|---|---|---|---|---|---|
3D | 1,300±100 | 0.08±0.02 | 3.5(±0.8) × 1016 | 9(±4) × 105 (Trap-assisted) | 7(±3) × 10−10 | 3(±2) × 10−28 | — |
MQWs | 22±2 | 0.60±0.05 | Lower than 3 × 1013* | 5(±3) × 107 (Excitonic) | 2(±0.6) × 10−9 | 2(±1) × 10−26 | — |
2D (n=2) | —† | —† | —† | —† | — | — | 0.10±0.02 |
2D (n=1) | 0.25±0.03 | 0.02±0.01 | —‡ | 4.0(±0.4) × 109 (Both) | — | — | 0.44±0.09 |
TQW, thicker quantum well; 2D, two dimensional; 3D, three dimensional.
*The trap states density associated with the TQWs (n≥5) in the MQWs film.
†We could not achieve pure quasi-2D (n=2) perovskite bulk crystal film.
‡2D (n=1) perovskite is not stable under high-power laser excitation.