Table 2.
1H NMR data (500 MHz) and 13C NMR data (125 MHz) of 3 and 4.
No. | 3 a | 4 b | ||
---|---|---|---|---|
δC | δH | δC | δH | |
1 | 172.9 C | 170.6 C | ||
3 | 70.0 CH2 | 5.18, s | 69.2 CH2 | 5.30, s |
3a | 144.1 C | 147.5 C | ||
4 | 116.7 C | 117.0 C | ||
5 | 163.8 C | 162.8 C | ||
6 | 122.5 C | 117.9 C | ||
7 | 153.7 C | 153.5 C | ||
7a | 106.3 C | 107.8 C | ||
8 | 11.6 CH3 | 2.13, s | 11.3 CH3 | 2.09, s |
9 | 61.1 CH3 | 3.77, s | 60.6 CH3 | 3.67, s |
1′ | 21.3 CH2 | 2.66, m | 118.2 CH | 6.63, d (16.5) |
2′ | 33.1 CH2 | 1.90, m | 137.4 CH | 6.76, d (16.1) |
1.67, m | ||||
3′ | 39.4 CH | 2.50, dq (6.9, 6.9) | 85.8 C | |
4′ | 177.0 C | 34.0 CH2 | 2.24, m | |
2.19, m | ||||
5′ | 51.6 CH3 | 3.68, s | 28.8 CH2 | 2.64, m |
2.56, m | ||||
6′ | 17.1 CH3 | 1.21 d (1.2) | 177.0 C | |
7′ | 26.4 CH3 | 1.55, s |
a CDCl3 used as solvent. b DMSO-d6 used as solvent.