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. Author manuscript; available in PMC: 2017 Dec 7.
Published in final edited form as: J Am Chem Soc. 2016 Nov 28;138(48):15559–15562. doi: 10.1021/jacs.6b09657

Scheme 1.

Scheme 1

Proposed Pathway for the Conversion of (−)-Lomaiviticin A (1) to (−)-Lomaiviticin C (2) and the Double Hydrodediazotization Product 3 via the Vinyl Radical Intermediates 1· and 2·