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. 2017 Mar 7;7:43503. doi: 10.1038/srep43503

Table 1. Thermodynamic parameters for the complexation of glutarimidedioxime with Mn2+ and UO2 2+.

Reaction logβ H kJ∙mol−1 S J∙mol−1∙K−1 ref
H+ + A2− = HA 12.27 ± 0.03 −36.1 ± 0.5 110 ± 2 17,21
2 H+ + A2− = H2A 23.15 ± 0.12 −69.7 ± 0.9 202 ± 3 17,21
3 H+ + A2− = H3A+ 25.67 ± 0.12 −77.0 ± 6.0 218 ± 14 17,21
Mn2+ + H++ A2− = MnHA+ 16.67 ± 0.12 −44.5 ± 0.6 170 ± 4 This work
Mn2+ + 2A2− = MnA22− 12.78 ± 0.12 −44.6 ± 1.2 95 ± 6 This work
UO22+ + H++ A2− = UO2HA+ 22.7 ± 1.3 −71.0 ± 6.0 197 ± 14 17
UO22+ + 2A2− = UO2A22− 27.5 ± 2.3 −101 ± 10 188 ± 24 17