Table 3.
Activation energy of the CNCs, calculated by the three methods in the range of a = 0.1 to 0.8.
Conversion Rate | Friedman | F-W-O | Coats-Redfern | |||
---|---|---|---|---|---|---|
E (KJ/mol) a | R2 | E (KJ/mol) a | R2 | E (KJ/mol) a | R2 | |
0.1 | 242.6 (±0.2) | 0.9959 | 239.0 (±0.2) | 0.9955 | 242.7 (±0.2) | 0.9952 |
0.2 | 289.9 (±0.1) | 0.9972 | 285.2 (±0.2) | 0.9971 | 291.2 (±0.2) | 0.9968 |
0.3 | 302.2 (±0.3) | 0.9999 | 299.4 (±0.2) | 0.9996 | 305.9 (±0.2) | 0.9995 |
0.4 | 304.9 (±0.3) | 0.9984 | 302.3 (±0.1) | 0.9974 | 308.9 (±0.1) | 0.9972 |
0.5 | 305.3 (±0.3) | 0.9976 | 295.0 (±0.2) | 0.9984 | 300.8 (±0.2) | 0.9982 |
0.6 | 311.7 (±0.3) | 0.9836 | 304.8 (±0.1) | 0.9721 | 310.8 (±0.1) | 0.9704 |
0.7 | 356.1 (±0.3) | 0.9899 | 343.0 (±0.1) | 0.9721 | 350.5 (±0.2) | 0.9769 |
0.8 | 387.9 (±0.3) | 0.9933 | 353.5 (±0.1) | 0.9782 | 360.9 (±0.1) | 0.9973 |
Mean | 312.6 (±0.3) | 0.9945 | 302.8 (±0.2) | 0.9888 | 309.0 (±0.2) | 0.9914 |
E: Apparent energy of activation; a: Values from CNCs with standard deviation.