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. Author manuscript; available in PMC: 2017 Nov 22.
Published in final edited form as: Biochemistry. 2016 Nov 14;55(46):6363–6374. doi: 10.1021/acs.biochem.6b00635

Figure 5.

Figure 5

A: NRVS spectra (top) and simulations (bottom) for low-spin ferric BLM showing an axial hydroxide bound to the Fe. B: NRVS data (top) and simulations (bottom) for ABLM. The three-peak pattern in the data can only be modeled by a low-spin FeIII-OOH structure. C: Schematic depictions of vibrations assigned in B. Adapted from ref 55.