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. Author manuscript; available in PMC: 2018 Mar 14.
Published in final edited form as: Rapid Commun Mass Spectrom. 2016 Dec 15;30(23):2462–2470. doi: 10.1002/rcm.7739

Figure 5.

Figure 5

MALDI-TOF/TOF-MS of m/z 525.030 that is observed in the MALDI-TOF-MS spectrum of Figure 4A (where the sample tested was an eluate of a urine-exposed PEP). This accurate mass fits both a sulfate, glucuronide conjugate of apigenin and genistein (exact mass 525.034), as does the fragmentation pattern seen here. For illustration purposes, the structure of apigenin-7-sulfate-4′-glucuronide is shown.