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. 2017 Mar 20;7:44599. doi: 10.1038/srep44599

Table 2. Substrate Scope of wt-CalB and Ser105Ala catalyzed BV-oxidation.

Entry Substrate Product wt-CalB
Ser105Ala
Conversion (%) Selectivity (%) Conversion (%) Selectivity (%)
1 Inline graphic Inline graphic 99 93 99 100
2 Inline graphic Inline graphic 95 48 51 97
3 Inline graphic Inline graphic 92 46 47 99
4 Inline graphic Inline graphic 79 35 38 96

General conditions: ketone (1 mmol), 30% aq. H2O2 (2 mmol), octanoic acid (1 mmol), 5 mg CalB (wild-type or S105A), ChCl/sorbitol (1.2 g), H2O (0.3 mL). T = 40 °C, time 48 h.