Table 2.

Thermodynamic parameters for reversible activation and irreversible inactivation of SCP production pathway of T. harzianum.

Temp. (K)	Temp. (°C)	q p  (g/gh) × 10−2	ΔH∗  (kJ mol−1)	ΔG∗  (kJ mol−1)	ΔS∗  (J mol−1 K−1)
293	20	8.5 ± 0.44c,d	35.06 ± 2a	72.52 ± 3.5b,c	−127.85 ± 8a,b
295	22	9.2 ± 0.45c	35.05 ± 2a	78.49 ± 3.5a,b,c	−147.25 ± 9b,c
297	24	9.7 ± 0.45b,c	35.045 ± 2a	82.76 ± 4a,b	−160.66 ± 10c
299	26	10.6 ± 0.51a,b	35.01 ± 2a	74.14 ± 3.5a,b,c	−231.2 ± 17d
301	28	11.3 ± 0.55a	37.0 ± 2.3a	67.66 ± 3.5c	−101.86 ± 7a
303	30	9.4 ± 0.41b,c	34.08 ± 2a	80.2 ± 4a,b	−152.21 ± 10b,c
305	32	8.8 ± 0.42c,d	34.06 ± 2a	80.91 ± 4a,b	−153.61 ± 10b,c
307	34	7.6 ± 0.43d,e	34.05 ± 2a	81.83 ± 4a,b	−155.64 ± 10b,c
309	36	6.6 ± 0.34e,f	34.03 ± 2a	82.75 ± 4a,b	−157.67 ± 10b,c
311	38	5.8 ± 0.34f	34.02 ± 2a	83.63 ± 4a	−159.52 ± 10c
P		0.0001	0.754	0.0001	0.0001

^a,b,c,d,e,fValues followed by different superscripts in each column differ significantly at confidence level P ≤ 0.05 using Tukey's multiple range test.

ΔG^∗ (kJ mol⁻¹) = −RTln⁡(q_P · h)/(k_B · T) and ΔS^∗ = (ΔH^∗ − ΔG^∗)/T.

ΔH^∗, ΔG^∗, and ΔS^∗ are enthalpy, Gibbs free energy, and entropy of irreversible inactivation of SCP formation pathway, respectively.