Table 1. A, B, C. Composition Profile of the SCCPs, MCCPs, and LCCPs, Sample Concentration Attributed (ng/g dw), Total SCCP, MCCP, and LCCP Concentration in ng/g dw, Goodness of fit (R2) and the Chlorination Degree in the Sewage Sludge Samplesa.
SCCPs
percent contribution |
sample
conc. (ng/g dw) attributed |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
A | C10 | C11 | C12 | C13 | SCCP 63% Cl | SCCP 55.5% Cl | SCCP 51.5% Cl | total SCCP conc. (ng/g dw) | R2 | Cl-degree (%) |
S1 | 6 | 22 | 21 | 50 | 80 | 64 | 12 | <156 | 0.65 | 60.9% |
S2 | 8 | 13 | 30 | 49 | 34 | 479 | 306 | 820 | 0.84 | 57.9% |
S3 | 28 | 45 | 8 | 19 | 57 | 73 | 0 | <130 | 0.16 | 61.6% |
S4 | 10 | 24 | 21 | 45 | 229 | 738 | 454 | 1421 | 0.76 | 59.5% |
S5 | 8 | 21 | 24 | 46 | 180 | 116 | 0 | 296 | 0.72 | 62.2% |
S6 | 3 | 20 | 26 | 51 | 137 | 178 | 0 | 315 | 0.70 | 61.2% |
S7 | 4 | 16 | 25 | 55 | 55 | 30 | 0 | <85 | 0.75 | 62.4% |
S9 | 10 | 13 | 23 | 54 | 60 | 422 | 202 | 685 | 0.64 | 58.6% |
S10 | 17 | 32 | 15 | 37 | 25 | 122 | 0 | <147 | 0.60 | 58.9% |
S11 | 18 | 0 | 15 | 67 | 23 | 34 | 0 | <57 | 0.24 | 60.8% |
S12 1 | 1 | 4 | 55 | 39 | 32 | 54 | 0 | <86 | 0.59 | 60.7% |
S12 2 | 0 | 0 | 59 | 41 | 22 | 38 | 0 | <60 | 0.58 | 61.0% |
S13 | 2 | 4 | 22 | 72 | 6 | 411 | 17 | 435 | 0.55 | 57.8% |
S14 | 5 | 21 | 26 | 48 | 56 | 12 | 16 | <83 | 0.69 | 62.4% |
S15 | 5 | 20 | 22 | 52 | 177 | 148 | 0 | 325 | 0.68 | 61.6% |
S16 | 13 | 28 | 22 | 37 | 218 | 186 | 1 | 406 | 0.65 | 63.0% |
Bl1 | 25 | 59 | 12 | 4 | 6** | 0** | 3** | 9** | 0.002 | 66.2% |
Bl2 | 29 | 53 | 12 | 7 | 7** | 0** | 9** | 16** | 0.001 | 64.0% |
MCCPs
percent contribution |
sample
conc. (ng/g dw) attributed |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
B | C14 | C15 | C16 | C17 | MCCP 42% Cl | MCCP 52% Cl | MCCP 57% Cl | total MCCP conc. (ng/g dw) | R2 | Cl-degree(%) |
S1 | 47 | 29 | 14 | 9 | 159 | 0 | 402 | 561 | 0.89 | 56.7% |
S2 | 45 | 31 | 15 | 8 | 1082 | 1582 | 486 | 3150 | 0.86 | 53.5% |
S3 | 32 | 38 | 19 | 11 | 114 | 250 | 345 | 710 | 0.61 | 55.6% |
S4 | 51 | 32 | 11 | 6 | 1303 | 1656 | 686 | 3645 | 0.95 | 54.0% |
S5 | 42 | 32 | 15 | 10 | 264 | 0 | 898 | 1162 | 0.85 | 56.5% |
S6 | 39 | 32 | 18 | 11 | 662 | 0 | 1110 | 1772 | 0.82 | 55.3% |
S7 | 39 | 35 | 16 | 9 | 216 | 16 | 484 | 716 | 0.78 | 56.5% |
S9 | 45 | 35 | 13 | 7 | 107 | 2555 | 529 | 3192 | 0.89 | 54.3% |
S10 | 40 | 34 | 16 | 11 | 0 | 386 | 427 | 813 | 0.81 | 54.9% |
S11 | 29 | 38 | 20 | 14 | 69 | 21 | 700 | 790 | 0.56 | 56.0% |
S12 1 | 33 | 39 | 17 | 11 | 0 | 181 | 814 | 995 | 0.71 | 55.9% |
S12 2 | 29 | 40 | 19 | 11 | 74 | 266 | 676 | 1016 | 0.60 | 55.2% |
S13 | 40 | 36 | 14 | 9 | 0 | 2242 | 1208 | 3449 | 0.81 | 54.6% |
S14 | 35 | 33 | 18 | 15 | 204 | 0 | 338 | 542 | 0.68 | 56.3% |
S15 | 42 | 33 | 15 | 9 | 0 | 0 | 974 | 974 | 0.84 | 57.5% |
S16 | 44 | 33 | 14 | 9 | 600 | 0 | 875 | 1474 | 0.86 | 56.0% |
Bl1 | 78 | 21 | 1 | 0 | 24** | 0** | 0** | 24** | 0.93 | 49.5% |
Bl2 | 78 | 20 | 2 | 0 | 22** | 0** | 0** | 22** | 0.90 | 49.0% |
LCCPs
percent contribution |
sample
conc. (ng/g dw) attributed |
||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
C | C18 | C19 | C20 | C21 | C22 | C23 | C24 | C25 | C26 | C27 | LCCP 36% Cl | LCCP 49% Cl | total LCCP conc. (ng/g dw) | R2 | Cl-degree (%) |
S1 | 26 | 13 | 13 | 7 | 6 | 5 | 9 | 6 | 7 | 7 | 0 | 116 | 116 | 0.42 | 44.1% |
S2 | 29 | 10 | 10 | 6 | 8 | 7 | 10 | 7 | 6 | 7 | 129 | 317 | 446 | 0.64 | 42.3% |
S3 | 29 | 12 | 9 | 5 | 7 | 4 | 10 | 9 | 7 | 7 | 0 | 156 | 156 | 0.47 | 44.9% |
S4 | 16 | 6 | 6 | 4 | 5 | 4 | 5 | 5 | 4 | 45 | 260 | 554 | 814 | 0.05 | 39.9% |
S5 | 22 | 11 | 10 | 5 | 7 | 11 | 11 | 10 | 6 | 7 | 0 | 364 | 364 | 0.29 | 45.0% |
S6 | 34 | 12 | 11 | 5 | 8 | 6 | 7 | 6 | 6 | 6 | 0 | 349 | 349 | 0.71 | 45.1% |
S7 | 32 | 18 | 12 | 6 | 8 | 7 | 6 | 5 | 4 | 3 | 0 | 154 | 154 | 0.50 | 48.3% |
S9 | 18 | 8 | 8 | 6 | 9 | 12 | 13 | 11 | 9 | 6 | 172 | 788 | 960 | 0.32 | 42.7% |
S10 | 27 | 12 | 11 | 6 | 9 | 10 | 10 | 7 | 4 | 4 | 0 | 305 | 305 | 0.57 | 43.9% |
S11 | 30 | 11 | 8 | 6 | 7 | 8 | 10 | 7 | 7 | 5 | 0 | 250 | 250 | 0.53 | 47.1% |
S12 1 | 11 | 6 | 4 | 5 | 8 | 13 | 17 | 15 | 12 | 9 | 0 | 625 | 625 | 0.11 | 42.5% |
S12 2 | 12 | 5 | 4 | 4 | 7 | 14 | 17 | 17 | 11 | 9 | 0 | 527 | 527 | 0.09 | 43.2% |
S13 | 31 | 12 | 8 | 6 | 7 | 10 | 10 | 7 | 6 | 4 | 0 | 683 | 683 | 0.67 | 46.0% |
S14 | 24 | 13 | 12 | 6 | 8 | 8 | 10 | 7 | 6 | 6 | 0 | 137 | 137 | 0.33 | 47.2% |
S15 | 24 | 13 | 11 | 7 | 9 | 9 | 8 | 7 | 6 | 6 | 0 | 398 | 398 | 0.40 | 46.5% |
S16 | 29 | 14 | 13 | 7 | 8 | 6 | 7 | 7 | 5 | 5 | 0 | 270 | 270 | 0.51 | 46.4% |
Bl1 | 0 | 0 | 0 | 0 | 0 | 0 | 42 | 29 | 29 | 0 | 0.2** | 0.2** | 0.4 | 0.00 | 33.2% |
Bl2 | 0 | 0 | 0 | 0 | 0 | 0 | 21 | 41 | 38 | 0 | 0.3** | 0.2** | 0.5 | 0.00 | 33.4% |
** = levels for the blanks are reported in ng abs. Italic = R2 lower than 0.5 therefore reported as tentative values.