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Sequential Bond Dissociation Free Energies (kJ/mol) of M+(L)x complexes for π-ligands. Uncertainties in parentheses [61].
| M+ | L = (C6H6) | L = (MeC6H5) | L = (N,N-Me2-C6H5) | |||
|---|---|---|---|---|---|---|
| x = 1 | x = 2 | x = 1 | x = 2 | x = 1 | x = 2 | |
| Li+ | 161 (14) | 104 (7) | 183 (16) | 117 (3) | 210 (8) | 128 (4) |
| Na+ | 93 (6) | 80 (6) | 112 (4) | 87 (2) | 129 (4) | 99 (2) |
| K+ | 74 (4) | 68 (7) | 80 (5) | 75 (5) | 99 (3) | 76 (3) |
| Rb+ | 69 (4) | 63 (8) | 71 (4) | 68 (4) | 92 (2) | 72 (3) |
| Cs+ | 65 (5) | 59 (8) | 64 (4) | 62 (4) | 83 (2) | 66 (3) |
