Table 4.

¹H and ¹³C chemical shifts (δ in ppm) and diffusion coefficients (D × 10⁻¹⁰ in m² s⁻¹) of the free octylamine ligand and 1:2 mixtures of octylamine and silver carboxylate at 25 °C in C₆D₆. Octanoic acid and acetic acid are listed as references for the corresponding insoluble silver salts

	1H and 13C NMR peak position (in ppm) and diffusion coefficients (D × 10−10 in m2 s−1)
	AcAc, OctAc, OA	[AgOAc-2OA]	[AgOct-2OA]	[AcAc-2OA]	[OctAc-2OA]
1H
−CH3 (AcAc)	1.52	2.32	–	2.22	–
α-CH2 (OctCOO−)	2.06	–	2.6		2.51
α-CH2 (OA)	2.51	2.66	2.73	2.65	2.64
−CH3 (OctCOO−)	0.86	–	0.92		0.90
−CH3 (OA)	0.90	0.93	0.94	0.90	0.90
13C
−COO−(AcAc)	178.46	178.88	–	178.88	–
−CH3 (AcAc)	20.57	24.70	–	25.65	–
−COO−(OctCOO−)	181.45	–	180.10	–	181.49
α-CH2 (OctCOO−)	34.55	–	38.88	–	39.46
α-CH2 (OA)	43.02	44.65	44.56	41.54	41.59
−CH3 (OctCOO−/OA)	14.63/14.71	14.73	14.75/14.72	14.7	14.72
D
log D (AcAc−)	–	4.3	–
log D (OctCOO−)	11.4	4.3	3.9
log D (OA)	17.9	10.6	7.2