Table 4. Impact of the Structure of the Acyl Moiety in Regio- and Enantioselective C–H Oxidation of N-Cyclohexyl Amides with (S,S)-Mn(^TIPSecp) as Catalyst.

^aNormalized ratio.

^bK₄ yields determined by GC.

^cRecovered starting material = 78%.

^d(R,R)-Mn(^TIPSecp).

^eAcetic acid (17 equiv) instead of cyclopropanecarboxylic acid.

^fYield determined by GC.

^gProducts isolated as mixture of (K₃ + K₄).

^hEe not determined. Ee’s determined by chiral GC and HPLC.