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. 2016 Nov 3;8(2):1613–1620. doi: 10.1039/c6sc03374a

Table 2. Stern–Volmer experiments performed with the photocatalysts a .

Photocatalyst 1 a
Photocatalyst 2 a
K SV [mM–1] k q b [108 M–1 s–1] K SV [M–1] k q b [108 M–1 s–1]
17 1.56 ± 0.05 6.4 ± 0.2 0.89 ± 0.07 7.6 ± 0.6
18 0.24 ± 0.03 1.0 ± 0.1 0.039 ± 0.006 0.32 ± 0.05
3a Quenching not observed c Quenching not observed c

aAll of the experiments were carried out in oxygen-free acetonitrile at 298 K with a photocatalyst concentration of 0.015 mM, with excitation at 330 nm. Data are reported with a ±95% confidence interval. In all cases, the quality of the fitting is assured by a R 2 > 0.98.

b k q = K SV/τ 0, where τ 0 is the unquenched excited-state lifetime of the photocatalyst.

cThere is no evidence of there being correlation between the excited-state quenching of the photocatalyst and the increasing amounts of 3a up to a concentration of 4 mM.