Table 2. Stern–Volmer experiments performed with the photocatalysts a .
| Photocatalyst 1
a
|
Photocatalyst 2
a
|
|||
| K SV [mM–1] | k q b [108 M–1 s–1] | K SV [M–1] | k q b [108 M–1 s–1] | |
| 17 | 1.56 ± 0.05 | 6.4 ± 0.2 | 0.89 ± 0.07 | 7.6 ± 0.6 |
| 18 | 0.24 ± 0.03 | 1.0 ± 0.1 | 0.039 ± 0.006 | 0.32 ± 0.05 |
| 3a | Quenching not observed c | Quenching not observed c | ||
aAll of the experiments were carried out in oxygen-free acetonitrile at 298 K with a photocatalyst concentration of 0.015 mM, with excitation at 330 nm. Data are reported with a ±95% confidence interval. In all cases, the quality of the fitting is assured by a R 2 > 0.98.
b k q = K SV/τ 0, where τ 0 is the unquenched excited-state lifetime of the photocatalyst.
cThere is no evidence of there being correlation between the excited-state quenching of the photocatalyst and the increasing amounts of 3a up to a concentration of 4 mM.