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. 2016 Dec 5;8(3):2352–2364. doi: 10.1039/c6sc03775e

Table 1. Electrochemical data of 1a–4a and 1b–4b a .

Complex E pc b /V E pa c /V
1a –1.79 d
2a 0.61, 0.95
3a –1.61 d 1.44
4a –1.50 d 0.71, 1.14
1b –1.82, –2.03 1.25
2b –1.89 0.59, 1.02
3b –1.59, –1.95 1.42
4b –1.49 d , –2.02 0.74

a Values determined in CH2Cl2 (Cp2Fe+/0 occurs at E 1/2 = +0.15–0.16 V) at 298 K; values reported versus Ag/AgNO3 reference electrode; electrolyte: 0.1 M nBu4NPF6; scan rate = 100 mV s–1.

b Cathodic peak potential (E pc) of irreversible wave.

c Anodic peak potential of (E pa) irreversible wave.

d E 1/2 = E pa + E pc of quasi-reversible wave.