Table 1. Photoirradiation products detected and characterized by LC-HRMS (according to Fig. S4).
Peak | RT (min) | MS (m/z) | Formula calculated m/z | Error (ppm) |
A | 7.4 | 344.0794 | Cis-[RuII(bpy)2(INH)2]2+ | 0.87 |
C32H30N10O2Ru: 344.0797 | ||||
B | 8.1 | 284.5553 | Cis-[RuII(bpy)2(INH)(H2O)]2+ | 0.70 |
C26H25N7O2Ru: 284.5555 | ||||
C | 3.2 | 128.0663 | [INH + H]+ | 0.72 |
C6H7N3O: 138.0662 | ||||
D | 8.9 | 225.0306 | Cis-[RuII(bpy)2(H2O)2]2+ | 2.67 |
C20H20N4O2Ru: 225.0312 | ||||
E | 4.3 | 224.5273 | Trans-[RuIII(bpy)2(H2O) (OH)]2+ | 0.00 |
C20H19N4O2Ru: 224.5273 | ||||
F | 6.7 | 225.0304 | Trans-[RuII(bpy)2(H2O)2]2+ | 1.03 |
C20H20N4O2Ru: 225.0312 |