Table 1. Permeation properties of the single and double-layered ZIF membranes fabricated inside P84 HF supports in the pre-combustion H2/CO2 mixture separation. Permeances and separation selectivities at 35 and 150 °C are shown, together with the 99% confidence intervals of each measure. Pure ZIF-9@P84 membrane values were averaged from two different membranes.
H2 permeance at 35 °C |
α H2/CO2 | H2 permeance at 150 °C |
α H2/CO2 | |||
mol m–2 s–1 Pa–1 | GPU | mol m–2 s–1 Pa–1 | GPU | |||
ZIF-8/ZIF-9@P84 | 12.2 ± 2.4 × 10–9 | 36 | 5.2 ± 0.7 | 83.9 ± 0.4 × 10–9 | 250 | 9.6 ± 0.1 |
ZIF-67/ZIF-9@P84 | 9.9 ± 0.5 × 10–9 | 29 | 5.4 ± 0.4 | 53.3 ± 0.2 × 10–9 | 159 | 9.0 ± 0.0 |
ZIF-9@P84 | 14.1 ± 3.2 × 10–9 | 42 | 4.8 ± 0.1 | 71.9 ± 0.2 × 10–9 | 215 | 8.0 ± 0.1 |
ZIF-8@P84 | 11.8 ± 0.1 × 10–9 | 35 | 4.1 ± 0.0 | 65.9 ± 1.1 × 10–9 | 197 | 7.4 ± 0.1 |