Table 2. Apparent activation energies calculated from an Arrhenius plot of the natural logarithm of the permeance values as a function of the inverse of temperature in the 35–150 °C range for the single and double-layered ZIF membranes (see Fig. S8).
E a,H2/kJ mol–1 | E a,CO2/kJ mol–1 | |
ZIF-8/ZIF-9@P84 | 18.1 | 12.2 |
ZIF-67/ZIF-9@P84 | 16.3 | 11.4 |
ZIF-9@P84 | 13.7 | 8.8 |
ZIF-8@P84 | 16.2 | 10.6 |