Table 2.

¹³C NMR Chemical Shifts of Ulapualides A-E (1–5) in CDCl₃

position	1		2		3		4		5
	δCa,b	type	δCa,b	type	δCa,b	type	δCa,c	type	δCa,c	type
1	172.5	C	172.5	C	172.5	C	172.6	C	172.4	C
2	43.0	CH2	43.0	CH2	43.0	CH2	43.4	CH2	42.8	CH2
3	68.1	CH	68.1	CH	68.0	CH	69.0	CH	68.3	CH
4	37.1	CH2	37.1	CH2	37.1	CH2	37.5	CH2	37.0	CH2
5	20.8	CH2	20.7	CH2	20.8	CH2	29.8	CH2	20.5	CH2
6	43.8	CH2	43.7	CH2	43.8	CH2	36.8	CH2	43.7	CH2
7	210.5	C	210.4	C	210.5	C	71.2	CH	210.0	C
8	47.8	CH2	47.7	CH2	47.7	CH2	45.4	CH2	47.8	CH2
9	27.4	CH	27.3	CH	27.3	CH	31.1	CH	27.4	CH
9-Me	19.6	CH3	19.6	CH3	19.7	CH3	19.3	CH3	19.4	CH3
10	146.3	C	146.3	C	146.3	C	146.8	C	146.1	C
11	133.5	CH	133.5	CH	133.5	CH	133.8	CH	133.2	CH
12	154.1	C	154.1	C	154.1	C	154.4	C	153.8	C
13	130.1	C	130.0	C	129.8	C	NDd		NDd
14	137.3	CH	137.3	CH	137.3	CH	137.0	CH	NDd
15	156.1	C	156.0	C	156.1	C	156.2	C	155.8	C
16	131.5	C	131.4	C	131.5	C	NDd		NDd
17	137.7	CH	137.7	CH	137.7	CH	137.3	CH	NDd
18	162.7	C	162.7	C	162.7	C	162.9	C	162.4	C
19	116.9	CH	116.8	CH	116.8	CH	115.9	CH	116.9	CH
20	139.9	CH	140.0	CH	140.1	CH	141.4	CH	139.7	CH
21	33.8	CH2	33.9	CH2	34.0	CH2	35.0	CH2	33.4	CH2
22	79.9	CH	79.9	CH	79.9	CH	78.3	CH	79.6	CH
22-OMe	57.7	CH3	57.7	CH3	57.8	CH3	58.1	CH3	57.6	CH3
23	40.3	CH	40.3	CH	40.4	CH	41.0	CH	40.1	CH
23-Me	9.0	CH3	8.9	CH3	9.0	CH3	9.0	CH3	9.0	CH3
24	72.8	CH	72.9	CH	72.9	CH	72.6	CH	72.6	CH
25	31.9	CH2	31.8	CH2	32.1	CH2	33.6	CH2	31.6	CH2
26	81.7	CH	81.6	CH	81.1	CH	81.6	CH	81.4	CH
26-OMe	58.0	CH3	57.9	CH3	58.1	CH3	58.0	CH3	57.8	CH3
27	34.4	CH	34.7	CH	35.5	CH	34.5	CH	34.4	CH
27-Me	15.4	CH3	15.5	CH3	15.4	CH3	15.7	CH3	15.6	CH3
28	25.0	CH2	27.0	CH2	28.4	CH2	25.2	CH2	26.6	CH2
29	39.8	CH2	30.4	CH2	29.7	CH2	39.8	CH2	30.3	CH2
30	211.6	C	73.03	CH	70.0	CH	211.6	C	72.7	CH
31	48.6	CH	37.5	CH	39.7	CH	48.6	CH	37.2	CH
31-Me	13.3	CH3	9.7	CH3	8.5	CH3	13.6	CH3	9.1	CH3
32	77.2	CH	79.8	CH	79.3	CH	77.2	CH	76.4	CH
32-OAc	170.0	C	170.6	C	172.5	C	170.0	C	171.1	C
	20.8	CH3	20.9	CH3	20.9	CH3	20.9	CH3	20.8	CH3
33	36.8	CH	36.9	CH	36.5	CH	36.9	CH	36.7	CH
33-Me	18.8	CH3	19.3	CH3	19.4	CH3	19.0	CH3	19.4	CH3
34	110.4	CH	110.2	CH	110.0	CH	110.5	CH	109.5	CH
35	129.4	CH	129.4	CH	129.4	CH	129.4	CH	129.4	CH
35-NMe	27.5	CH3	27.5	CH3	27.5	CH3	27.5	CH3	27.5	CH3
35-NCHO	162.1	CH	162.1	CH	162.1	CH	162.1	CH	161.9	CH
36			170.2	C					170.3	C
37			80.6	CH					81.4	CH
37-OMe			58.6	CH3					58.2	CH3
38			72.98	CH2					62.9	CH2
38-OMe			59.3	CH3

^aCarbon spectra recorded at 125 MHz.

^bResonances for minor rotamers can be found in the supporting information.

^cCarbon resonances extrapolated from HSQC and HMBC experiments.

^dNot detected.